Chemical Reaction between Tantalum and Gallium under High Pressure

CHEMICAL REACTION AT HIGH TEMPERATURE AND HIGH PRESSURE VI Polymorphic Transition in ZnP, at High Temperature and High Pressure

:1 new pressure-induced modification of zincdiphosphide, ZnP2, has been prepared by the di reel union o(zinc with phosphorus and also through the polymorphic transitions of both monoclinic and tetragonal ZnP2. The application of pressures above 20 kb combined with temperatures above 150'C is required for [be synthesis. The new modification of ZnP2 has a pseuda•cuhic cps[al symmetry with a latti...

Optical fiber-based on-line UV/Vis spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor.

With a miniaturized (3 microL volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants (at different pressures) and the activation volumes (deltaV(not =)) were determined for a nucleophilic aromatic substitution and an aza Diels-Alder reaction in a capillary microreactor.

High performance under pressure.

Nanomaterials under high-pressure.

The use of high-pressure for the study and elaboration of homogeneous nanostructures is critically reviewed. Size effects, the interaction between nanostructures and guest species or the interaction of the nanosystem with the pressure transmitting medium are emphasized. Phase diagrams and the possibilities opened by the combination of pressure and temperature for the elaboration of new nanomate...

High Pressure Cw Chemical Laser